Abstract

Review Article

Photocatalytic Degradation of Microcystins-LR over Mesoporous graphitic Carbon Nitride (mpg-CN)

Laiyan Wu*, Jirong Lan, Anping Yang, Yanxi Zhao, Songbo Wang and Junjiang Zhu*

Published: 24 May, 2017 | Volume 1 - Issue 1 | Pages: 012-22

Mesoporous graphitic carbon nitrides (mpg-CN) were synthesized by a templating method using Ludox (SiO2) as hard template and guanidine hydrochloride (GndCl) as precursor, and were used as metal-free photocatalysts for microcystin-LR (MC-LR) degradation in aqueous solution. By tuning the mass ratio of SiO2 to GndCl, mpg-CN with varied surface areas and condensation degrees were obtained. Catalytic results showed that sample prepared at mass ratio equals 0.4, i.e., mpg-CN(0.4), exhibits the best activity, with above 98% MC-LR conversion obtained at 120 min. Mechanism studies suggested that the reaction obeys the pseudo first-order equation and the produced superoxide anion radicals (•O2−) is the major reactive intermediates contributing to the reaction. Stability tests showed that no appreciable loss of activity is observed even the catalyst is recycled for five times, indicating that the material is stable in the reaction.

Read Full Article HTML DOI: 10.29328/journal.aac.1001002 Cite this Article Read Full Article PDF

Keywords:

Mpg-CN; Microcystin-LR; Photo degradation; Reusability; Mechanism

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